| 1. Product Name: | Brown 10P857 | Revision # |
4 |
Date: 10-Aug-2009 |
Company: |
The Shepherd Color Company 4539 Dues Drive Cincinnati, Ohio 45246 U.S.A. Shepherd Color International Serskampsteenweg 135A B-9230 Wetteren, Belgium Shepherd Color International 1st Floor, 479 Warrigal Rd Moorabbin, Victoria 3189 Australia Shepherd Color International Shinjuku Dai-ichi Seimei Building 4-F 2-7-1, Nishi-Shinjuku Shinjuku-ku Tokyo, Japan 163-0704 |
Telephone: |
U.S.A. Office: 513-874-0714 Belgium Office: +32-9-366-1111 Australian Office: +61-3-9532-5260 Japanese Office: +813-3344-3010 |
Emergency information: |
Telephone: Domestic Shipments: CHEMTREC 800-424-9300 International Shipments: CHEMTREC (703) 527-3887 |
2. Hazards Identification
| EEC Risk Phrases: | This document has been prepared in accordance with 91/155/EC. This product is not classified as hazardous according to {NOHSC:2011(1994)}& OHS Regulations 1999. |
| EEC Safety Phrases: | Not applicable |
| Methods for Cleanup: | See Section XI for Toxicological Information. |
3. Composition/Information on Ingredients
| % Weight | |||
| Ingredients: | CAS No: | EINECS | (Typical) |
| Zinc Iron Chromite Brown Spinel | 68186-88-9* | 269-050-0 | 100 |
| Synonyms: | BR0010P857 - BROWN 10P857 ; C.I. Pigment Brown 33; C.I. Constitution #77503; CPMA #13-37-7 |
| This product is the result of high temperature calcination of the component substances. Due to its unique crystalline structure the properties of this finished pigment do not necessarily reflect the properties of the component metals or oxides. ** |
4. First Aid Measures
| If inhaled: | If inhaled, remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician. |
| On ingestion: | If conscious, drink large quantities of water. Do Not induce vomiting. Get immediate medical attention. NEVER give anything by mouth to an unconscious person. |
| On contact with eyes: | On contact with eyes flush eyes with plenty of water for at least fifteen (15) minutes. Call a physician. |
| On skin contact: | On skin contact, wash thoroughly with soap and water. |
5. Fire Fighting Measures
| Suitable extinguishing media: | This product will not burn. Use suitable extinguishing media for fighting surrounding fire. |
| Unsuitable extinguishing media: | Not applicable |
| Emitted when burned: | Not applicable |
| Special protective equipment: | This product will not burn. Use appropriate techniques for fighting surrounding fire. |
| Further information: | None |
6. Accidental Release Measures
| Personal precautions: | Maintain appropriate dust control. |
| Environmental precautions: | Prevent contamination of soils, drains and surface water. |
| Methods for cleanup: | Transfer material into closed container for re-use or disposal. |
7. Handling and Storage
| Handling: | Good housekeeping procedures should be followed to prevent dust during processing. Do not eat, drink or smoke in work areas. Wash thoroughly with soap and water after handling. Provide eye wash stations in areas of handling. |
| Storage: | Store material in a closed container. Normal warehousing. |
8. Exposure Controls and Personal Protection
| Engineering controls/measures: | Use mechanical ventilation to keep dust below regulatory standards (see Section II). Design criteria usually cannot be specified in an MSDS because of its complexity. |
| Personal Protective Equipment: | |
| Respiratory protection: | MSHA/NIOSH respirators approved for dusts TC-21C or NIOSH approved cartridges for Non-oil aerosols, N95, N99, N100 (42 CFR 84). |
| Hand protection: | Rubber, PVC coated gloves, impermeable. |
| Eye protection: | Safety Glasses with side shields, mono goggles. |
| Body protection: | No special precautions (see hand protection). |
| General safety and hygiene measures: | Good housekeeping procedures should be followed to prevent dust during processing. |
| As Regulated | OSHA PEL | ACGIH TLV | %Metal | Sara | |
| (Related Exposure Limits) | (mg/m³) | (mg/m³) | (Typical) | 313 |
| Chromium (III) compounds (as Cr) | 0.5 | 0.5 | 17 | Yes | |
| Zinc compounds (as Zn) | None | 5 | 20 | Yes |
9. Physical and Chemical Properties
| Appearance: | Brown Powder | ||
| Odor: | No Odor | ||
| Melting point/melting range: | Not applicable | ||
| Boiling point/boiling range: | Not applicable | ||
| Flash point: | Not applicable | ||
| Combustibility: | Not applicable | ||
| Explosion limits: | |||
|
Not applicable | ||
|
Not applicable | ||
| Ignition temperature: | Not applicable | ||
| Self-ignition: | Not applicable | ||
| Self-ignition temperature: | Not applicable | ||
| Explosion hazard: | Not applicable | ||
| Fire promoting properties: | Not applicable | ||
| Vapor pressure: | Not applicable | ||
| Specific gravity: | 4.9 SCTM 312 | ||
| Bulk density: | No data available | ||
| Packing density: | 4.3 lbs/solid gallon (0.52 Kg/L) SCTM 194 (7) | ||
| Solubility in Water: | Negligible | ||
| Solubility in other solvents: | Negligible | ||
| pH value: | 8.4 SCTM 101 (7) | ||
| Octanol/water partition coefficient (log POW): | Not applicable | ||
| Viscosity: | Not applicable | ||
| Other information: | Not applicable |
10. Stability and Reactivity
| Conditions to avoid: | None known |
| Materials to avoid: | None known |
| Hazardous reactions: | None known |
| Hazardous decomposition products: | None known |
11. Toxicological Information
Acute Toxicity
| LD50/oral/rat: | >10,000 mg/kg (6) |
| LD50/inhal/rat: | Not Tested |
| Sensitizing: | None expected |
| Primary skin irritation/rabbit: | No data available |
| Primary mucous membrane irritation/rabbit' eyes: | No data available |
ADDITIONAL INFORMATION:
| Repeated overexposure to this compound may cause eye, skin and respiratory tract irritation. Some compounds of the metals used in the manufacturing of this pigment Chromium and Zinc, have demonstrated various toxic properties (1,2,3,4). However, there is no evidence that this pigment has these toxic characteristics. |
Routes of Entry:
Eyes: No Skin: No Inhalation: Yes Ingestion: Yes
| CARCINOGENICITY: NTP: | No | IARC Monographs: | No |
| OSHA Regulated: | No | ||
| Signs and Symptoms of Exposure: | Irritation of the eyes, skin and respiratory tract. |
| Medical Conditions Generally Aggravated by Exposure: | Respiratory and skin disorders aggravated by dust. |
12. Ecological Information
| Mobility: | No data available |
| Degradability: | No data available |
| Accumulation: | No data available |
| Short and long term effects on: | |
| Ecotoxicity: | No data available |
| Other adverse effects: | No data available |
13. Disposal Considerations
| Substance: | Dispose of at an approved landfill in accordance with local, state, federal and national regulations. |
| Contaminated packaging: | Dispose of at an approved landfill in accordance with local, state, federal and national regulations. |
14. Transportation information
INTERNATIONAL
Land transport: ADR/RID/GGVS/GGVE: Not Regulated
Sea transport: IMDG/GGVSee UN-No.: Not Regulated
Air transport: ICAO/IATA UN/ID-No.: Not Regulated
| U.S. | D.O.T. Classification: | Not Regulated |
| CANADA | Transport of dangerous goods: | Not Regulated |
15. Regulatory Information
Labeling according to EEC Directives: Not Regulated
SARA
SARA 312:
| Health: | Immediate (Acute): | No* | Fire: | None |
| Delayed (Chronic): | No** | Reactivity: | None | |
| Sudden release of pressure: | None |
| *Not an acute hazard, however may cause irritation due to abrasiveness. |
| **These products are not classified as Carcinogens by the National Toxicology Program, the International Agency for Research on Cancer or the Occupational Safety and Health Administration. We do not know of any chronic health effect from these products. The finished pigment is a fine powder and may increase the risk of respiratory and skin disorders aggravated by dust. |
SARA 313:
| THIS PRODUCT CONTAINS A CHEMICAL OR CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. THIS INFORMATION MUST BE INCLUDED IN ALL MSDS THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL. |
| 100% Chromium Compound |
| 100% Zinc Compound |
Inventories
| The ingredients of this product have been listed in the following inventories: |
|
HMIS Code: 100
16. Other Information
References:
1. |
Occupational Health Guidelines for Chemical Hazards, Vol. I., OSHA, Sept., 1978. |
2. |
Occupational Diseases "A Guide to Their Recognition", U.S. DHEW (NIOSH), June 1977. |
3. |
Documentation of the Threshold Limit Values, 6th Edition, ACGIH, 1991. |
4. |
Pocket Guide to Chemical Hazards, NIOSH/OSHA, June, 1997. |
5. |
The Merck Index (10th Edition), 1983. |
6. |
Acute Oral Toxicity Tests for Zinc Iron Chromite Brown Spinels, The Shepherd Color Company Data, 2/7/91. |
7. |
Technical Data Sheet, The Shepherd Color Company. |
| Although the information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed to be correct as of the date hereof, The Shepherd Color Company makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purpose prior to use. In no event will The Shepherd Color Company be responsible for damages of any nature whatsoever resulting from the use of or reliance upon Information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS. |